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61.
62.
Gian Paulo G. Freschi Carolina D. Freschi José A. Gomes Neto 《Mikrochimica acta》2008,161(1-2):129-135
Different kinds of modifiers and coatings on the integrated platform of transversely heated graphite atomizer (THGA) have
been tested for the simultaneous determination of two group of elements: the first, the more volatile, formed by arsenic,
bismuth, lead, antimony and selenium; the second, the less volatile, formed by cobalt, chromium, cupper, iron and manganese
in milk by electrothermal atomic absorption spectrometry. Different Rh-modifiers were studied, such as Rh-coated platforms
(Rh), carbide plus rhodium coated platforms (W-Rh, Zr-Rh), carbide-coated platforms (W and Zr) with co-injection of RhCl3, solutions and uncoated platforms with injection of solutions of Pd(NO3)2, Mg(NO3)2, and RhCl3. Milk samples were diluted 1:10 in 1.0% HNO3 and injected into the tube. The mass of modifier deposited and co-injected in the tube and the use of end capped tubes were
also evaluated in order to improve the electrothermal behavior of analytes. Integrated platform pretreated with W plus co-injection
RhCl3 for first group and pretreated with W-Rh for second group were elected. For 20 μL injected samples the analytical curves
in the 5.0–20.0 μg L−1 concentration range have good linear correlation coefficients (r > 0.998). Relative standard deviations (n = 12) are <6% and the calculated characteristic masses are between 5 pg and 62 pg.
Correspondence: Gian Paulo G. Freschi, Faculdade de Ciências Exatas e Tecnologia, Universidade Federal da Grande Dourados,
PO Box 332, 79.804-970, Dourados-MS, Brazil; Instituto de Química, Universidade Estadual Paulista, PO Box 355, 14801-970 Araraquara-SP,
Brazil 相似文献
63.
Thays de Souza Lima Fábio Ruiz Simões 《International journal of environmental analytical chemistry》2017,97(8):768-782
This study is aimed to develop an electroanalytical methodology using a boron-doped diamond electrode to determine simultaneously and selectively carbendazim (CBZ) and carbaryl (CAR). In previous studies using cyclic voltammetry oxidation, peaks were observed at 1.03 V (CBZ) and 1.44 V (CAR), with characteristics of an irreversible process controlled by diffusion of species, with a supporting electrolyte of BR buffer (0.1 mol L?1) and pH adjusted to 6.0. The differences between the potentials for both pesticides, about 400 mV, indicate the possibility of selective determination of CBZ and CAR. The square-wave voltammetric parameters were optimised. The best separation conditions were pH 6.0, square-wave frequency of 100 s?1, pulse amplitude of 50 mV and scan increment of 2.0 mV. These parameters were used to obtain the calibration curves of CBZ and CAR. An analytical curve was constructed in the range concentration of CBZ of 1.3 mg L?1 to 15.3 mg L?1 and CAR of 1.0 mg L?1 to 11.4 mg L?1, respectively. The limits of detection (LOD) and limits of quantification (LOQ) for CBZ were 0.40 mg L?1 and 1.30 mg L?1, respectively. For CAR, the LOD and LOQ were 0.30 mg L?1 and 1.00 mg L?1, respectively. Sensitivity values were 0.78 and 2.60 µA/mg L?1 for CBZ and CAR, respectively. The electroanalytical method was applied in Mikania glomerata infusions. The recovery values were 106.2% and 116.5% for CBZ and CAR, respectively. The results show that the developed method is suitable for application in medicinal plant samples. 相似文献
64.
Present docking methodologies simulate only one single ligand at a time during docking process. In reality, the molecular recognition process always involves multiple molecular species. Typical protein–ligand interactions are, for example, substrate and cofactor in catalytic cycle; metal ion coordination together with ligand(s); and ligand binding with water molecules. To simulate the real molecular binding processes, we propose a novel multiple ligand simultaneous docking (MLSD) strategy, which can deal with all the above processes, vastly improving docking sampling and binding free energy scoring. The work also compares two search strategies: Lamarckian genetic algorithm and particle swarm optimization, which have respective advantages depending on the specific systems. The methodology proves robust through systematic testing against several diverse model systems: E. coli purine nucleoside phosphorylase (PNP) complex with two substrates, SHP2NSH2 complex with two peptides and Bcl‐xL complex with ABT‐737 fragments. In all cases, the final correct docking poses and relative binding free energies were obtained. In PNP case, the simulations also capture the binding intermediates and reveal the binding dynamics during the recognition processes, which are consistent with the proposed enzymatic mechanism. In the other two cases, conventional single‐ligand docking fails due to energetic and dynamic coupling among ligands, whereas MLSD results in the correct binding modes. These three cases also represent potential applications in the areas of exploring enzymatic mechanism, interpreting noisy X‐ray crystallographic maps, and aiding fragment‐based drug design, respectively. © 2010 Wiley Periodicals, Inc. J Comput Chem, 2010 相似文献
65.
采用分子束外延技术生长了两个叠层结构的双色量子阱红外探测器结构,并经过光刻和湿法刻蚀制作成两端结构的量子阱红外探测器单元器件. 通过改变量子阱势垒高度,势阱宽度,掺杂浓度,重复周期数等器件参数,可以使总电压在两个叠层之间产生适当的分布,从而使器件表现出不同的电压响应特点. 光电流谱测量显示,器件1随着外加偏置电压可实现对于中波大气红外窗口(3—5 μm)和长波大气红外窗口(8—12 μm)红外响应的切换,器件2在不同的偏置电压下可以对这两个波段同时做出响应. 本文探讨了两端叠层结构量子阱红外探测器的工作原
关键词:
电压调制
同时响应
量子阱红外探测器
双波段 相似文献
66.
In the present paper, we deal with the complex Szasz-Durrmeyer operators and study Voronovskaja type results with quantitative estimates for these operators attached to analytic functions of exponential growth on compact disks. Also, the exact order of approximation is found. 相似文献
67.
Epi Erpina Latifah Kosim Darusman Arum Vitasari Budi Riza Putra Eti Rohaeti 《液相色谱法及相关技术杂志》2017,40(12):635-639
A new method for simultaneous quantification of curcuminoids and xanthorrhizol (XNT) in Curcuma xanthorrhiza was developed and validated using high-performance liquid chromatography with diode-array UV–Vis detector. The chromatographic separation was achieved on a Phenomenex C18 at room temperature with the mobile-phase acetonitrile ?0.001% formic acid in gradient elution system and delivered at a flow rate of 1?mL/min. Detection wavelength 425?nm was used for curcuminoids and 224?nm for XNT. System suitability, linearity, precision, accuracy, limit of detection, limit of quantitation, and stability were evaluated and were found in good agreement with Association of Official Analytical Chemists guidelines for single-laboratory validation. The proposed method was found to be precise, accurate, and reliable and also could be applied for the simultaneous quantitative analysis of curcuminoids and XNT in C. xanthorriza raw material and its herbal medicinal product. 相似文献
68.
Zhi‐Yong Guo Pan‐Pan Gai Jing Duan Jin‐Xia Zhai Sha‐Sha Zhao Sui Wang Dan‐Yi Wei 《Biomedical chromatography : BMC》2010,24(10):1094-1099
A gas chromatography–mass spectrometry assay was developed and validated for the simultaneous determination of phthalates and adipates in human serum. The phthalates and adipates studied were dimethyl phthalate, diethyl phthalate, dibutyl phthalate, benzylbutyl phthalate, di‐2‐ethylhexyl phthalate, di‐n‐octyl phthalate, diethyl adipate, dibutyl adipate, diisobutyl adipate, bis(2‐butoxyethyl) adipate and di‐2‐ethylhexyl adipate, with diisooctyl phthalate as internal standard. The extraction and cleaning up procedure was carried out with solid‐phase extraction cartridges containing dimethyl butylamine groups, which showed extraction efficiencies over 88% for each analyte and the internal standard. The calibration curves obtained were linear with correlation coefficients greater than 0.98. For all analytes, the assay gave CV% values for intra‐day precision from 4.9 to 13.3% and mean accuracy values from 91.4 to 108.4%, while inter‐day precision was 5.2–13.4% and mean accuracy 91.0–110.2%. The limits of detection for the assay of phthalates and adipates were in the range 0.7–4.5 ng/mL. The method is simple, sensitive and accurate, and allows for simultaneous determination of nanogram levels of phthalates and adipates in human serum. It was successfully applied to an investigation on the level of phthalates and adipates in a non‐occupationally exposed population. 相似文献
69.
Yuhui Wei Boxia Li Haogang Duan Xin'an Wu Xiaojun Yao 《Biomedical chromatography : BMC》2010,24(3):289-293
A large number of herb materials contain essential oils with extensive bioactivities. In this work, an integrated simultaneous distillation–extraction (ISDE) apparatus was developed. To demonstrate its feasibility, the performance of ISDE was evaluated for the extraction of essential oil from Flos Magnoliae and compared with conventional techniques including steam distillation (SD) and simultaneous distillation–extraction (SDE). According to the product yield, the time consumed and the composition of oil, the essential oils isolated by ISDE were better than that obtained by SD and similar to those obtained by SDE. ISDE was also better than SDE due to its simple operation and lower consumption of energy and organic solvent. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
70.
In this paper, we shall introduce and characterize simultaneous quasi-Chebyshev (and weakly-Chebyshev) subspaces of normed spaces with respect to a bounded set S by using elements of the dual space. 相似文献